Thymine nmr
Webb3 maj 2012 · Product Name Thymidine CAS 50-89-5 Molecular Formula C10H14N2O5 Molecular Weight 242.23 InChI InChI=1S/C10H14N2O5/c1-5-3-12 (10 (16)11-9 (5)15)8-2 … WebbThe melting temperature value ( Tm ), which is a measure of the binding affinity between the oligonucleotide and its target sequence, shows that 2- O -methylthymine can form a much “better” base pair with guanine than adenine, with the Tm values of DNAs containing these base pairs differing by 13.7 °C.
Thymine nmr
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WebbThymine = 99 65-71-4 ( 1) T0376 Thymine ≥99% Synonym (s): 2,4-Dihydroxy-5-methylpyrimidine, 5-Methyluracil Empirical Formula (Hill Notation): C5H6N2O2 CAS … Webb2 feb. 2016 · Thymine, Molecular mechanics, Conformation Abstract We report a disagreement between the predicted structures of the dTpT thymine pair (thymidylyl (3′ …
Webb29 dec. 2004 · Our study shows that NMR merely probes the presence/absence of the methyl group in thymine/uracil, without any relation to the strength of the hydrogen bonds involved. In other words, one cannot infer the Watson-Crick hydrogen-bond strength from the NMR shielding constant of adenine C2. WebbOne and two dimensional NMR techniques have been used together with molecular modelling to obtain the solution structure for the photoproduct d(TpA)*. The NMR data confirm that the cyclobutane linkage is formed between the bonds thymine C6-C5 and adenine C5-C6. The 2D NOE data are used as constraints in a distance geometry …
Webb2) 利用nmr研究许多重要酶在核酸复制过程中识别、剪切与修复核酸损伤位点的机制,以及相关蛋白与核酸相互作用机制。 3) 利用化学结构修饰(有机合成)与酶学方法研究与疾病相关的酶与底物相互作用机制。 WebbWe have determined the three-dimensional (3D) structure of DNA duplex that includes tandem Hg(II)-mediated T-T base pairs (thymine-Hg(II)-thymine, T-Hg(II)-T) with NMR spectroscopy in solution. This is the first 3D structure of metallo-DNA (covalently metallated DNA) composed exclusively of 'NATURAL …
Thymine (65-71-4) 1 H NMR Product Name Thymine CAS 65-71-4 Molecular Formula C5H6N2O2 Molecular Weight 126.11 InChI InChI=1S/C5H6N2O2/c1-3-2-6-5 (9)7-4 (3)8/h2H,1H3, (H2,6,7,8,9) InChIKey RWQNBRDOKXIBIV-UHFFFAOYSA-N Smiles C1 (=O)NC=C (C)C (=O)N1 Request For Quotation MS 1 HNMR 13 CNMR IR1 IR2 Raman ESR 400 MHz in DMSO-d6 Assign. Shift (ppm)
Webb22 maj 2014 · Miscible polymer blends featuring strong hydrogen bonding interactions are of interest to materials scientists, because they can exhibit improved or modified properties relative to those of their individual constituent polymers [1,2,3].The strength and extent of hydrogen bonding in copolymer or polymer blends depend on the respective … intracavernosal phenylephrine injectionWebb15 apr. 2009 · NMR studies have demonstrated that Hg(II) binds directly to N-3 of two thymidine residues in place of two imino protons and forms N–Hg ... Thymine-modified polymer sorbents were prepared by copolymerizing of allyl thymine (AT, Fig. 1 b) with ethylene dimethacrylate (EDMA) or by grafting of AT onto the surface of a support. intracavitary fibroidsWebb3 maj 2012 · Product Name Thymidine CAS 50-89-5 Molecular Formula C10H14N2O5 Molecular Weight 242.23 InChI InChI=1S/C10H14N2O5/c1-5-3-12 (10 (16)11-9 (5)15)8-2-6 (14)7 (4-13)17-8/h3,6-8,13-14H,2,4H2,1H3, (H,11,15,16)/t6-,7+,8+/m0/s1 InChIKey IQFYYKKMVGJFEH-XLPZGREQSA-N Smiles OC [C@H]1O [C@@H] (N2C=C (C)C … intracavitary fluid on ultrasoundWebbThymine C5H6N2O2 CID 1135 - structure, chemical names, physical and chemical properties, classification, patents, literature, biological … intracavitary gradient is suspectedWebb18 maj 2015 · Direct detection of the mercury-nitrogen bond in the thymine-Hg(II)-thymine base-pair with (199)Hg NMR spectroscopy newly momWebbIn this paper the NMR spectra of deoxytrinucleotides containing thymine, adenine and guanine in deuterium oxide solution are reported and discussed. Spectra of … newly modernWebb1050 Hz) within the HgII-mediated thymine–thymine base pair (T–HgII–T). This strikingly large 1J(199Hg,15N)isthefirstoneforcanonical sp2-nitrogen atoms, which can be a sensitive structure-probe of N-mercurated compounds and a direct evidence for N-mercuration. Mercury-199 NMR spectroscopy is used to probe coordination intracavernous sinus